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Mandavgane, Sachin A.
- Behaviour of Biomass Multicomponent Ashes as Adsorbents
Abstract Views :240 |
PDF Views:93
Authors
Affiliations
1 Department of Chemical Engineering, VNIT, Nagpur 440 010, IN
2 CSIR-National Chemical Laboratory, Pune 411 008, IN
1 Department of Chemical Engineering, VNIT, Nagpur 440 010, IN
2 CSIR-National Chemical Laboratory, Pune 411 008, IN
Source
Current Science, Vol 110, No 2 (2016), Pagination: 180-186Abstract
Physico-chemical characteristics of rice husk ash and baggase fly ash, commonly referred to as biomass ashes (BMA), enable their use as adsorbents. Contrary to normal expectations, it is observed that larger particles have more number, narrower and deeper pores than smaller particles. As a consequence they have higher pore volume, total surface area and hence adsorption capacity. Also, the uptake rate of adsorption depends on the silica to carbon ratio, which is seen to be smaller for larger particles and hence they take a longer time to reach equilibrium. The extent of carbon content determines the capacity, whereas silica to carbon ratio determines the kinetics of adsorption. Removal of 2,4-dichlorophenoxy acetic acid, from aqueous solution was chosen as a representative case for study and the results obtained are compared with earlier reported results.Keywords
Adsorption Capacity, Bagasse, Biomass Ash, Rice Husk, Silica to Carbon Ratio.Full Text
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- Use of Sugarcane Bagasse Ash as Brick Material
Abstract Views :483 |
PDF Views:115
Authors
Affiliations
1 National Institute of Construction Management and Research, Pune 411 045, IN
2 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, South Ambazari Road, Nagpur 440 010, IN
3 Department of Civil Engineering, Visvesvaraya National Institute of Technology, South Ambazari Road, Nagpur 440 010, IN
1 National Institute of Construction Management and Research, Pune 411 045, IN
2 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, South Ambazari Road, Nagpur 440 010, IN
3 Department of Civil Engineering, Visvesvaraya National Institute of Technology, South Ambazari Road, Nagpur 440 010, IN
Source
Current Science, Vol 107, No 6 (2014), Pagination: 1044-1051Abstract
Application of bio-fuel by-product sugarcane bagasse ash (SBA) as a principal raw material for the manufacturing of bricks was studied. The bricks were developed using the quarry dust (QD) as a replacement to natural river sand and lime (L) as a binder. SBA as a principal raw material was characterized using X-ray fluorescence (XRF), thermo-gravimetric analysis (TGA), X-ray diffraction and scanning electron microscopy (SEM). XRF confirms SBA as a cementitious material. TGA confirms thermal stability till 650°C, whereas SEM monograph shows individual ash with a rough surface and numerous fine pores. Elemental analysis of quarry dust and lime was also carried out using XRF and classic wet test. The physical properties of quarry dust and lime were determined using the laboratory test methods. SBA-QD-L combination bricks were designed and developed in different mix proportions. Physico-mechanical properties of the developed bricks were studied according to recommended standards. The results of the SBA-QD-L bricks were compared with physico-mechanical properties of commercially available burnt clay-and-flyash bricks. It was observed that SBA-QD-L bricks are lighter in weight, energy efficient and meet compressive strength requirements of IS 1077:1992. The bricks also serve the purpose of solid waste management and innovative sustainable construction material. The bricks can be used in local construction especially for non-load-bearing walls.Keywords
Bricks, Quarry Dust, Lime, Sugarcane Bagasse Ash.Full Text
- Characterizing Fruit and Vegetable Peels as Bioadsorbents
Abstract Views :223 |
PDF Views:84
Authors
Affiliations
1 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, Nagpur 440 010, IN
2 CSIR-National Chemical Laboratory, Pune 411 008, IN
1 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, Nagpur 440 010, IN
2 CSIR-National Chemical Laboratory, Pune 411 008, IN
Source
Current Science, Vol 110, No 11 (2016), Pagination: 2114-2123Abstract
Fruit and vegetable peel (FVP) wastes are a commonly generated organic waste from both households and food-processing industries. However, FVPs are low cost lignocellulosic materials that have some potential for reutilization. For its particular reutilization, the characterization of FVP is essential. In this regard, the present study provides a detailed physico-chemical characterization of commonly used FVPs such as pomegranate, pineapple, watermelon, garlic, green pea and pigeon pea. The materials were characterized by SEM, FTIR and TGA/DTG. Various properties of these materials, such as porosity, particle density, bulk density, surface charges, point of zero charge, surface pH, water absorption capacity and BET surface area were determined. The BET surface area of FVP was found in the range 1.0-1.4 m2/g. Water absorption capacity was highest for watermelon peel (11.5 ml/g), while it was lowest for pigeon pea peel (5.5 ml/g). Point of zero charge and surface pH of all FVPs were in the acidic range 3-6. The surface of FVP was irregular and rough with some pores. Thermal analysis showed that FVPs are thermally stable below 150°C. The results of this study provide an understanding of the properties of FVPs and suggest that the materials can be used as a low-cost adsorbent.Keywords
Bioadsorbent, Fruit and Vegetable Peels, Organic Waste, Physico-Chemical Characterization.Full Text
- Fruit Peel Waste:Characterization and its Potential Uses
Abstract Views :622 |
PDF Views:76
Authors
Affiliations
1 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, Nagpur 440 010, IN
2 CSIR-National Chemical Laboratory, Pune 411 008, IN
1 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, Nagpur 440 010, IN
2 CSIR-National Chemical Laboratory, Pune 411 008, IN
Source
Current Science, Vol 113, No 03 (2017), Pagination: 444-454Abstract
Globally, India is the leading producer of fruits. Fruits after consumption leave a peel which is a nuisance to the environment as a solid waste. In this article, commonly available large volume-fruit peels (FP) (viz. banana, orange, citrus, lemon and jackfruit) were investigated for surface, physical and chemical characteristics with a view to propose their valorization in detail. Each FP was characterized by proximate and ultimate analysis, porosity, particle density, bulk density, point of zero charge (pHpzc), surface pH, surface charges, water absorption capacity, BET surface area, scanning electron microscopy, Fourier transform infrared spectroscopy and TGA/derivative of thermogravimetric. The BET surface area of FP is very less, between 0.60 and 1.2 m2/g. The pHpzc and surface pH values of orange peel (OP), citrus peel (CP), lemon peel (LP) and jackfruit peels (JFP) are in the range of 3-4. The pHpzc value and surface pH of banana peel (BP) is closer to 7. The order of surface acidity is OP > LP > CP > JFP > BP. From TG curves it is clear that FPs are stable below 150°C. The results will be useful for rational design, when FP is used as a substrate for bioactive compounds, phenolic antioxidants, organic acids, enzymes, biofertilizer, production of energy and as adsorbents.Keywords
Characterization, Fruit Peel, Solid Waste, Utilization, Valorization.Full Text
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- Use of Biomass Ashes in Agriculture with Reference to Farming Practices in Vidarbha, Maharashtra, India
Abstract Views :218 |
PDF Views:67
Authors
Affiliations
1 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, Nagpur 440 010, IN
1 Department of Chemical Engineering, Visvesvaraya National Institute of Technology, Nagpur 440 010, IN
Source
Current Science, Vol 113, No 07 (2017), Pagination: 1384-1393Abstract
As a regular farming practice in India, especially in Vidarbha, biomass ashes (BMAs) are spread on farmland. BMA forms a protective layer on the soil surface and acts as a barrier, thereby preventing direct contact between pesticides and soil. BMA acts: (i) as an adsorbent for removal of pesticides; (ii) as a soil additive and water enhancer, and (iii) as a micronutrient source for plants. In this study, paraquat, a representative chemical was selected to prove the hypothesis that BMAs are the most efficient adsorbents of herbicides used in Vidarbha. The adsorption capacity (mg/m2) of BFA for removal of paraquat was found to be greater than that reported for natural adsorbents. Based on adsorption capacity, RHA and BFA dosages per hectare of land are recommended for different crops and fruits.Keywords
Adsorption, Bagasse Fly Ash, Biomass Ash, Paraquat, Rice Husk Ash.Full Text
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